Issue 51, 2021
From the journal:

Chemical Communications

Modulating photoswitch performance with halogen, coordinative and hydrogen bonding: a comparison of relative bond strengths†

Sofia Lindblad, ORCID logo a   Daniel Sethio, ORCID logo a   Orion B. Berryman*b  and  Máté Erdélyi ORCID logo *a  

* Corresponding authors

a Department of Chemistry–BMC, Uppsala University, Uppsala SE-751 23, Sweden
E-mail: Mate.Erdelyi@kemi.uu.se

b Department of Chemistry and Biochemistry, 32 Campus Drive, University of Montana, Missoula, Montana 59812, USA
E-mail: Orion.Berryman@mso.umt.edu

Abstract

The behavior of an enediyne photoswitch is modulated with halogen bonding, coordinative bonding and hydrogen bonding. Through NMR and computational studies we demonstrate that the relative strength of the secondary bonding directly influences the rate of photoisomerization and the photostationary state.

Graphical abstract: Modulating photoswitch performance with halogen, coordinative and hydrogen bonding: a comparison of relative bond strengths

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Article information

DOI
https://doi.org/10.1039/D1CC01827B
Article type
Communication
Submitted
06 Apr 2021
Accepted
25 May 2021
First published
25 May 2021
This article is Open Access
Creative Commons BY license

Chem. Commun., 2021,57, 6261-6263

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Modulating photoswitch performance with halogen, coordinative and hydrogen bonding: a comparison of relative bond strengths

S. Lindblad, D. Sethio, O. B. Berryman and M. Erdélyi, Chem. Commun., 2021, 57, 6261 DOI: 10.1039/D1CC01827B

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